This has been achieved 33 times, although some players have done it more than once. This will be apparent from this table:

From this we can identify the “multibaggers” as
IT Botham 5 times (1978, 1978, 1980, 1981, 1984)
R Ashwin 3 times (2011, 2016, 2021)
JH Kallis 2 times (1999, 2002)
Mushtaq Mohammad 2 times (1973, 1977)
Shakib Al Hasan 2 times (2011, 2014)
GS Sobers 2 times (1962, 1966).
We can also see that Botham (1980), Imran (1983) and Shakib (2014) went a step further by scoring a century and taking 10 wickets in the match.
BR Taylor (1965) was the only one to score a century and take 5wi on his Test debut. This was his first first-class century.
[…] Hope you have read the related piece https://abn397.wordpress.com/2021/02/19/the-double-of-a-century-and-5wi-in-the-same-test/ […]
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